Overcoming fundamental challenges in emerging PV
Emerging PV technologies cells have a continuous strong track record in performance during the last
years. With these performance values, solution processed emerging photovoltaic technologies are
reaching out to applications that are going beyond the typical niche markets. The first generation of
commercially available printed PV modules showed a lifespan in the order of beyond 5 years and
more under outdoor conditions (OPV) while long-time outdoor data for perovskite modules are still
missing. Interestingly, several experiments are strongly suggesting that solution processed
semiconductors like organics or perovskites can be stable under light and, to some extent, under
oxygen as well. Despite these impressive numbers, one should not forget that these are “best you
can do” lifetime values.
On the other hand, the community did not progress significantly in overcoming the fundamental
limitations of printed PV. This is more expressed for organics than for perovskites: The energy gap
law for excitonic materials, the precise microstructure control of binary or ternary composites, the
design principles for environmentally stable materials or the Kirchhoff law for multi-junction cells
continue to be major barriers for this technology.
We briefly introduce into these long-time challenges and then discuss concepts and strategies how
to resolve them for excitonic absorbers. Among them, the development of a digital twin which has
inverse predictive power is a most promising concept. “Solar FAU”, an alliance of research partners
in the Erlangen-Nürnberg region that is headed by Friedrich Alexander University, is exploring the
basic concepts and methodologies how to build a digital twin for emerging-PV technologies. The
central and most desired element of the digital twin is the power of inverse design, e.g., inventing
molecules, device architectures and processes with tailored properties. Insight from first pieces
(agents) of the digital twin strongly supports the assumption that inverse design capability is
possible, even in the case of considerable experimental uncertainty. Coupling the digital twin to
Material Acceleration Platforms (MAP) reduces experimental uncertainty and allows to learn
predictions which otherwise would be impossible. We have recently demonstrated the power of
such coupled systems and demonstrated correlations which were previously unthinkable, like the
prediction of performance and lifetime of OPV cells from simple absorption data or the identification
of he best process for perovskites under environmental conditions merely at the hand of
photoluminescence data.
Emerging PV technologies cells have a continuous strong track record in performance during the last
years. With these performance values, solution processed emerging photovoltaic technologies are
reaching out to applications that are going beyond the typical niche markets. The first generation of
commercially available printed PV modules showed a lifespan in the order of beyond 5 years and
more under outdoor conditions (OPV) while long-time outdoor data for perovskite modules are still
missing. Interestingly, several experiments are strongly suggesting that solution processed
semiconductors like organics or perovskites can be stable under light and, to some extent, under
oxygen as well. Despite these impressive numbers, one should not forget that these are “best you
can do” lifetime values.
On the other hand, the community did not progress significantly in overcoming the fundamental
limitations of printed PV. This is more expressed for organics than for perovskites: The energy gap
law for excitonic materials, the precise microstructure control of binary or ternary composites, the
design principles for environmentally stable materials or the Kirchhoff law for multi-junction cells
continue to be major barriers for this technology.
We briefly introduce into these long-time challenges and then discuss concepts and strategies how
to resolve them for excitonic absorbers. Among them, the development of a digital twin which has
inverse predictive power is a most promising concept. “Solar FAU”, an alliance of research partners
in the Erlangen-Nürnberg region that is headed by Friedrich Alexander University, is exploring the
basic concepts and methodologies how to build a digital twin for emerging-PV technologies. The
central and most desired element of the digital twin is the power of inverse design, e.g., inventing
molecules, device architectures and processes with tailored properties. Insight from first pieces
(agents) of the digital twin strongly supports the assumption that inverse design capability is
possible, even in the case of considerable experimental uncertainty. Coupling the digital twin to
Material Acceleration Platforms (MAP) reduces experimental uncertainty and allows to learn
predictions which otherwise would be impossible. We have recently demonstrated the power of
such coupled systems and demonstrated correlations which were previously unthinkable, like the
prediction of performance and lifetime of OPV cells from simple absorption data or the identification
of he best process for perovskites under environmental conditions merely at the hand of
photoluminescence data.